5.1.1 The atom
An atom has a tiny, dense, positively charged nucleus at its centre. Electrons (negatively charged) orbit the nucleus.
| Particle | Relative charge | Relative mass |
|---|---|---|
| proton | ||
| neutron | ||
| electron | about (very small) |
A neutral atom has equal numbers of protons and electrons, so the charges cancel.
The alpha-particle scattering experiment
In this experiment, a beam of alpha particles (positive) was fired at a very thin sheet of gold foil, and a detector was moved round to count the particles at different angles.
| Observation | What it shows |
|---|---|
| most alpha particles went straight through | an atom is mostly empty space |
| a few were deflected through large angles, and a very few bounced almost straight back | the nucleus is very small and holds a concentrated mass |
| the particles that were deflected were repelled | the nucleus is positively charged (it repels positive alpha particles) |
So the experiment provides evidence for a very small nucleus surrounded by mostly empty space, a nucleus that contains most of the mass of the atom, and a nucleus that is positively charged.
5.1.2 The nucleus
The nucleus is made of protons and neutrons, which are together called nucleons.
An atom becomes an ion when it gains or loses electrons:
- losing electrons gives a positive ion (more protons than electrons);
- gaining electrons gives a negative ion.
A nuclide is a particular type of nucleus. It is written in nuclide notation: , where X is the chemical symbol.
- Protons: .
- Neutrons: .
- Electrons in a neutral atom: .
Isotopes are atoms of the same element (the same ) with different numbers of neutrons (different ). They have the same chemical properties. Carbon-12 and carbon-14 are isotopes of carbon: both have 6 protons, but they have 6 and 8 neutrons. An element can have more than one isotope.
5.2.1 Detection of radioactivity
- Alpha particles can be detected with a cloud chamber (they leave visible tracks) or a spark counter.
- Beta particles and gamma radiation are detected with a Geiger–Müller (GM) tube connected to a counter.
The counter gives the count rate, measured in counts per second or counts per minute.
Background radiation
Background radiation is the low level of radiation that is always present. The main sources are:
- radon gas in the air (from rocks),
- rocks and buildings,
- food and drink,
- cosmic rays from space.
To measure only a source, first measure the count rate with no source present (the background), then with the source, and subtract.
5.2.2 The three types of emission
Some nuclei are unstable and give out radiation to become more stable. The emission is spontaneous (it is not caused by anything outside the nucleus) and random (we cannot tell when a particular nucleus will decay, or in which direction the radiation will go).
| Alpha () | Beta () | Gamma () | |
|---|---|---|---|
| what it is | two protons and two neutrons (a helium nucleus) | a high-speed electron from the nucleus | high-frequency electromagnetic wave |
| charge | none | ||
| ionising effect | strongest | medium | weakest |
| penetrating power | stopped by paper or a few centimetres of air | stopped by a few millimetres of aluminium | reduced by thick lead or concrete |
Deflection in fields.
- In an electric field, alpha particles are deflected slightly towards the negative plate, beta particles are deflected more (they are much lighter) towards the positive plate, and gamma rays are not deflected because they have no charge.
- In a magnetic field, alpha and beta are deflected in opposite directions (they have opposite charges, and you can find the direction with Fleming's left-hand rule), and gamma rays are not deflected.
5.2.3 Radioactive decay
Radioactive decay is a change in an unstable nucleus that can give out -particles or -particles, and/or -radiation. It is spontaneous and random.
Decay equations. In an equation, the total of the nucleon numbers (top) and the total of the proton numbers (bottom) must each be the same on both sides.
- Alpha decay. The nucleus loses 2 protons and 2 neutrons. decreases by 4 and decreases by 2.
- Beta decay. A neutron in the nucleus changes into a proton and an electron, and the electron is emitted. stays the same and increases by 1.
- Gamma emission. A nucleus that has just emitted an alpha or beta particle often has extra energy, and gets rid of it as gamma radiation. and do not change.
The daughter nucleus has nucleon number and proton number , which is radon (Rn):
5.2.4 Fission and fusion
Fusion
Fusion is the joining of two small nuclei to make a larger nucleus, releasing energy. It needs very high temperatures and pressures, because the nuclei repel each other. Fusion is the energy source for stars: the Sun fuses hydrogen into helium.
Fission
Fission is the splitting of a large nucleus. A uranium-235 nucleus absorbs a neutron and splits into two smaller daughter nuclei, plus two or more neutrons, and releases energy.
Chain reaction. The neutrons given out can be absorbed by other uranium-235 nuclei and make them split too. If each fission leads to more than one further fission, the reaction grows rapidly and can run out of control, as in a nuclear bomb.
In a nuclear reactor the chain reaction is controlled:
| Part | Job |
|---|---|
| fuel rods | contain the uranium-235 |
| moderator (graphite or water) | slows the neutrons down so they are more likely to cause fission |
| control rods (boron or cadmium) | absorb neutrons; lowering them into the reactor slows the reaction, and raising them speeds it up |
| coolant (water or carbon dioxide) | carries away the thermal energy to a boiler to make steam, which drives the turbine and generator |
5.2.5 Half-life
hours is half-lives, so the count rate is halved three times:
days is half-lives: , so is left.
Carbon dating
Living things take in carbon, including a small constant fraction of radioactive carbon-14. When a living thing dies, no more carbon-14 is taken in, and what is there decays with a half-life of about years. Measuring the activity of carbon-14 in an old object and comparing it with that of living material shows how long ago it died.
A quarter is two halvings, so two half-lives: years.
Choosing an isotope for a job
The right isotope depends on the type of radiation it emits and its half-life.
| Use | Radiation chosen | Why |
|---|---|---|
| smoke alarm | alpha (americium-241) | alpha ionises the air in a small chamber so a small current flows; smoke absorbs the alpha particles and the current falls, setting off the alarm. Alpha is safe because it cannot leave the alarm. A long half-life means it lasts for years |
| irradiating food | gamma | gamma is penetrating and kills bacteria all through the food, and does not make the food radioactive |
| sterilising medical equipment | gamma | it can sterilise instruments after they have been sealed in packaging |
| measuring and controlling the thickness of paper or metal foil | beta (for thin paper or foil) or gamma (for thick metal) | a source on one side, a detector on the other; if the material is too thick, fewer particles get through and the count falls, so the rollers are adjusted. The radiation must be partly, not wholly, absorbed, so the thinner the material, the less penetrating the radiation chosen. Alpha would be fully stopped |
| diagnosing and treating cancer | gamma | gamma passes out of the body to be detected (diagnosis) or can be aimed at a tumour to kill the cells (treatment). A tracer used for diagnosis has a short half-life, so it does not stay radioactive in the body for long |
5.2.6 Safety precautions
Ionising radiation can damage or kill cells, and mutate the DNA in them, which can lead to cancer.
Radioactive materials are moved, used and stored safely by:
- reducing the time of exposure (work quickly, and keep sources locked away when not in use);
- increasing the distance between the source and the person (use tongs or long handles, because the radiation gets weaker with distance);
- using shielding to absorb the radiation (lead or thick concrete walls, and sources kept in lead-lined containers).
Sources are clearly labelled, kept in locked, shielded stores, and people who work with them wear badges that record how much radiation they have received.
Practise this chapter
Every past-paper question on these topics, with the mark scheme.

