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Chemistry · May / June 2023 · Paper 42 · Question 4

0620

As printed in the paper

The question as text

Solid sodium hydroxide is a base which dissolves to form an aqueous solution, NaOH(aq).

Read automatically from the paper; the printed page above is exact.

Show the answer and mark scheme
  • 4(a)[1]

    proton acceptor

  • 4(b)[1]

    alkali

  • 4(c)[1]

    blue

  • 4(d)[3]

    M1 sodium chloride

    M2 water

    M3 ammonia

  • 4(e)(i)[1]

    amphoteric (oxides)

  • 4(e)(ii)[1]

    aluminium oxide

    or

    zinc oxide

  • 4(f)(i)[3]

    M1 all single bonding dot and cross pairs correct

    M2 double C = O bond dot and cross pairs are correct

    M3 complete diagram is correct

  • 4(f)(ii)[1]

    3≤ pH < 7

    CH3COOH ⇌ CH3COO– + H+

  • 4(f)(iii)[3]

    M3 use of ⇌

    M1 H+

    M2 CH3COO–

  • 4(f)(iv)[1]

    H+ + OH– → H2O

  • 4(g)[5]

    M1 mol KOH = 0.0800 × 25 / 1000

    = 0.002(00) / 2(00) × 10–3

    M2 mol H2SO4 = M1 / 2 = 0.002 / 2

    = 0.001(00) / 1(00 × 10–3

    M3 = M2 × 1000 / 20 = 0.001 × 1000 / 20

    = 0.05(00) / 5.(00) × 10–2

    M4 = 98

    M5 = 98 × M3 = 98 × 0.05(00) = 4.9(0) (g / dm3)

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