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Chemistry · May / June 2023 · Paper 11 · Question 11

5070Electrolysis

Concentrated aqueous sodium chloride is electrolysed using inert electrodes. Which row shows what happens in this electrolysis and why it happens?

  1. Aoxygen is discharged at the anode; OH–(aq) loses electrons more easily than Cl–(aq)
  2. Bduring electrolysis the pH of the electrolyte increases; the electrolysis in aqueous solution involves the reduction of H+(aq) ions
  3. Csolid sodium is produced at the cathode; Na+(aq) is present in aqueous solution
  4. Dthe products stay the same if the aqueous sodium chloride is replaced by molten sodium chloride; Na+ and Cl– are present in both molten and aqueous sodium chloride

As printed in the paper

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Correct answer: B. during electrolysis the pH of the electrolyte increases; the electrolysis in aqueous solution involves the reduction of H+(aq) ions

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