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Chemistry · May / June 2022 · Paper 12 · Question 3

5070Identification of ions and gases

Some reactions of an aqueous solution of compound X are given. - When a few drops of aqueous sodium hydroxide are added, a white precipitate is formed. - When dilute nitric acid is added and the mixture is warmed, a gas is formed. The gas decolourises acidified potassium manganate(VII). - When dilute nitric acid and aqueous barium nitrate are added, no visible reaction occurs. What can be deduced about the identity of X?

  1. AX contains only aluminium sulfate, Al2(SO4)3.
  2. BX contains only calcium sulfite, CaSO3.
  3. CX must contain aluminium sulfite, Al2(SO3)3, or zinc sulfite, ZnSO3.
  4. DX must contain aluminium sulfite, Al2(SO3)3, calcium sulfite, CaSO3, or zinc sulfite, ZnSO3.

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Correct answer: D. X must contain aluminium sulfite, Al2(SO3)3, calcium sulfite, CaSO3, or zinc sulfite, ZnSO3.

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