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Chemistry · May / June 2020 · Paper 11 · Question 3

5070Chromatography

A paper chromatography experiment is carried out to find an $R_f$ value for Fe$^{3+}$(aq). The result is shown. [diagram: chromatogram with solvent front, starting line, spot labelled Fe$^{3+}$, distances $y$ and $x$] To make the spot containing Fe$^{3+}$(aq) more visible, the paper is sprayed with aqueous sodium hydroxide so that a precipitate of iron(III) hydroxide forms. Under the conditions of the experiment, the $R_f$ of Fe$^{3+}$(aq) is given by ......1...... and the colour of the precipitate is ......2...... . Which row correctly completes gaps 1 and 2?

  1. Agap 1: $\frac{x}{y}$; gap 2: red-brown
  2. Bgap 1: $\frac{x}{y}$; gap 2: green
  3. Cgap 1: $\frac{y}{x}$; gap 2: red-brown
  4. Dgap 1: $\frac{y}{x}$; gap 2: green

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Correct answer: A. gap 1: $\frac{x}{y}$; gap 2: red-brown

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