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Chemistry · May / June 2023 · Paper 41 · Question 4

0620

As printed in the paper

The question as text

Oxygen is produced by the decomposition of aqueous hydrogen peroxide. Manganese(IV) oxide, MnO2, is a catalyst for this reaction.

Read automatically from the paper; the printed page above is exact.

Show the answer and mark scheme
  • 4(a)[2]

    M1 increases the rate of reaction /

    speeds up a reaction(1)

    M2 unchanged at the end of the reaction(1)

  • 4(b)(i)[1]

    oxygen escapes from the flask or apparatus

    concentration of hydrogen peroxide is highest at the start / particles of hydrogen peroxide are closest together at the start

  • 4(b)(ii)[1]

    OR

    collision frequency is highest at the start

  • 4(b)(iii)[1]

    the hydrogen peroxide is used up /

    ALL the hydrogen peroxide has reacted or decomposed

  • 4(c)[3]

    M1 kinetic energy of particles increases(1)

    M2 frequency of collisions between particles increases(1)

    M3 more or higher percentage or higher proportion or

    higher fraction of particles have energy greater than / equal to activation energy

    OR

    more of the collisions or higher percentage or higher fraction of collisions have energy greater than or equal to activation energy(1)

  • 4(d)[3]

    M1 (50.0 × 0.200 ÷ 1000 =) 0.01(1)

    M2 0.005(1)

    M3 0.16(0)(1)

  • 4(e)[1]

    no effect

    2HgO → 2Hg + O2

  • 4(f)[2]

    M1 all formulae correct(1)

    M2 equation correct(1)

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