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Chemistry · Oct / Nov 2022 · Paper 42 · Question 3

0620

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The question as text

Sulfuric acid is manufactured by an industrial process. Sulfur is obtained from sulfur-containing metal ores. The sulfur in the metal ore is converted to sulfur dioxide which is then oxidised to sulfur trioxide as shown. 2SO2(g) + O2(g) 2SO3(g)

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  • 3(a)[1]

    zinc blende

  • 3(b)[1]

    strong heating in air / roasting in air

  • 3(c)[1]

    contact

  • 3(d)(i)[2]

    M1 450 (°C) (1)

    M2 1–2 (atm) (1)

  • 3(d)(ii)[1]

    vanadium(V) oxide

  • 3(d)(iii)[2]

    M1 the rate of forward reaction equals (the rate of the) reverse reaction (1)

    M2 concentrations of reactants and products are constant (1)

  • 3(d)(iv)[4]

    increased temperature:

    M1 (position of) equilibrium moves to left-hand side (1)

    M2 reaction is exothermic (1)

    increased pressure:

    M3 (position of) equilibrium moves to right-hand side (1)

    M4 more (gaseous) moles / molecules on left-hand side (1)

  • 3(d)(v)[3]

    M1 rate increases and particles have more energy (1)

    M2 more collisions (between particles) occur per second / per unit time (1)

    M3 more of the particles / collisions have energy equal to or above the activation energy (1)

    or

    more of the particles / collisions have sufficient energy to react

    or

    a higher percentage / proportion / fraction of collisions (of particles) are successful / have energy equal to or above activation energy

  • 3(e)[1]

    ammonium sulfate

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