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Chemistry · Oct / Nov 2021 · Paper 41 · Question 2

0620

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The question as text

This question is about copper and its compounds.f 63 6

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  • 2(a)(i)[1]

    isotopes

  • 2(a)(ii)[3]

    1 mark for each correct row

    63Cu

    65Cu2+

    p

    29

    29

    n

    34

    36

    e

    29

    27

  • 2(a)(iii)[2]

    M1 = (70 × 63) + (30 × 65) or [ ( 4410) + (1950) ] or 6360 (1)

    M2 = M1 / 100 = 63.6 (1)

    OR

    M1= (0.7(0) × 63) + (0.3(0) × 65) or [ (44.1(0) ) + (19.5(0)) ] (1)

    M2 = 63.6 (1)

  • 2(b)(i)[2]

    M1 white (1)

    M2 to (light) blue (1)

  • 2(b)(ii)[1]

    5H2O

  • 2(b)(iii)[1]

    heating

  • 2(b)(iv)[2]

    M1 boiling point (1)

    M2 is 100 °C

    OR

    M1 freezing point (1)

    M2 is 0 °C (1)

  • 2(c)(i)[1]

    blue precipitate

  • 2(c)(ii)[3]

    Alternative suggestion:

    M1 Cu(OH)2 (as only product) (1)

    M2 Cu2+ and 2OH– (as reactants) (1)

    M3 state symbols (1)

  • 2(d)[4]

    M1 188

    M2 4.7 / 188 = 0.025(0)

    M3 0.025(0) × 2 = 0.05(0)

    M4 0.05(0) × 24.0 = 1.2

  • 2(e)[2]

    2NaNO3 → 2NaNO2 + O2

    NaNO2 (1)

    rest of equation (1)

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